312 Questions

TIRF evanescent excitation field is D nm, generate an approximate expression for

the SNR of the spots using such TIRF excitation.

b

Explain under what conditions it might be suitable to use TIRF to monitor gene

expression of these proteins.

7.7

If two crystal structures, A and B, for a given protein molecule M are possible that

both have roughly the same interfacial energies and saturation values, but structure B

has a more open conformation such that the mean volume per molecule in the crystal

is greater than that in structure A by a factor of ~2, explain with reasoning what rela­

tive % proportion by number of crystals one might expect when crystals are grown

spontaneously from a purified supersaturated solution of M.

7.8

Platinum wire of length 20 cm and diameter 75 μm was wound around a tungsten

electrical resistance heating filament that was then heated to evaporate all of the plat­

inum 3 cm away from the surface of a glass coverslip surface of size 22 × 22 mm

under high vacuum to coat the surface in a thin layer of platinum for manufacturing

an optical filter. The coated coverslip was used in an inverted fluorescence micro­

scope flow cell for detecting a specific protein that was labeled with a single fluores­

cent dye molecule, conjugated to the coated coverslip surface. If the brightness of a

single fluorescently labeled protein on an identical coverslip not coated in platinum

was measured at ~7600 counts under the same imaging conditions, estimate with

reasoning what range of spot brightness values you might observe for the case of

using the platinum-​coated coverslip. (Assume that the optical attenuation is roughly

linear with thickness of the platinum layer, equivalent to ~15% at 50 nm thickness,

and wavelength is independent across the visible light spectrum.)

7.9

A leak-​free horizontal microfluidics device of length 15 mm was made consisting of

three cylindrical pipes each of length 5 mm with increasing diameters of 10, 20, and

30 μm attached end to end. If the flow was gravity driven due to a reservoir of fluid

placed 50 cm above the entrance of the flow cell connected via low-​friction tubing,

estimate the time it takes for a 1 μm bead to flow from one end of the flow cell to

the other.

7.10 A competing flow-​cell design to Question 7.9 was used, which consisted of three

pipes of the same diameters as the previous but each of length 15 mm connected this

time in parallel. How long will a similar bead take to flow from one end of the flow

cell to the other?

7.11 High-​throughput methods for measuring protein–​protein interaction kinetics using

cell lysate analysis in vitro can generate large errors compared to the in vivo kin­

etics. Give a specific example of a protein–​protein interaction whose kinetics can be

measured inside a living cell using a biophysical technique. What are the challenges to

using such assays for systems biology? Suggest a design of apparatus that might pro­

vide high-​throughput measurement and automated detection?

7.12 In internal radiotherapy for treating a thyroid gland of a total effective diameter of

4 cm using a small ionizing radiation source at its center to treat a central inner tumor

with a diameter of 1 cm, estimate with reasoning and stating assumptions what pro­

portion of healthy tissue will remain if 99% of the tumor tissue is destroyed by the

treatment.

7.13 In developing a simple microfluidics-​based pH sensor for biological samples, two par­

allel input channels, one containing a biological fluid sample of unknown pH, and

the other containing a fluid pH indicator which changes color on mixing with the

sample, were pumped under laminar flow into a single common detection chamber.

In the first design, a color change in the detection chamber was observed only beyond

a distance of ~3 mm from the point of entry of both input flow channels, whereas in

a second design which had chevron shapes etched into the detection chamber sur­

face the color changed after more like ~1 mm distance from the point of entry. Why

is this?